Electronic Communication in Heterometallated Porphyrin Oligomers - Springer Theses - Jonathan Cremers - Libros - Springer Nature Switzerland AG - 9783030391034 - 14 de febrero de 2021
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Jonathan Cremers
Electronic Communication in Heterometallated Porphyrin Oligomers - Springer Theses 2020 edition

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This book cuts across the divisions of organic, inorganic, and physical chemistry. It describes new methods for creating ?-conjugated porphyrin oligomers with precisely defined sequences of zinc and copper metal cations, and how EPR spectroscopy was used to investigate the dipolar and exchange coupling between the paramagnetic copper(II) centres.

Porphyrins are a group of heterocyclic macrocycle organic compounds that play an important role in our everyday life and can for example be found in blood where they form a red complex with iron (haem). Various metallic elements can be inserted into a porphyrin and changing the coordinated metal is an excellent way to influence the chemical and physical properties of these molecules.

Focusing on 3 metals - zinc, magnesium and copper - the author established new methods for creating ?-conjugated porphyrin oligomers and lastly presents the synthesis and investigation of two novel porphyrin nanoballs. Giving the template-directed strategy the author developed for constructing these molecules, this work could provide access to other related nano-cages.


255 pages, 338 Tables, color; 334 Illustrations, color; 16 Illustrations, black and white; XLI, 255

Medios de comunicación Libros     Paperback Book   (Libro con tapa blanda y lomo encolado)
Publicado 14 de febrero de 2021
ISBN13 9783030391034
Editores Springer Nature Switzerland AG
Páginas 255
Dimensiones 150 × 220 × 10 mm   ·   421 g
Lengua Alemán  

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